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Lyocell / Tencel: Facts behind the Fiber

What is Tencel Lyocell?
Tencel® is the
brand name for a recently improved fabric from a
fiber generically called lyocell.
Under the “Textile,
Wool, and Fur Labeling Acts” of the U.S.
Government, man-made and natural fibers must be
identified by their generic names. What this
means according to U.S. law is that garment labels
that say Tencel®
should actually be labeled as lyocell.
When you identify fiber content on a label, or in
advertising, you must use the generic fiber name
recognized by the Federal Trade Commission. A
trademark name alone does not suffice. Of course,
Tencel® is the commonly known name and few
actually call the fabric by its generic name
lyocell. We will use the proper generic name
lyocell. Remember that Tencel® is just the brand
name for a type of lyocell.
Lyocell is a natural,
man-made fiber produced in an
environmentally-friendly process from wood pulp
that has become popular in clothing because it is
absorbent and
comfortable for wear, especially in conditions of
high humidity. Lyocell also drapes attractively
and is flattering in dresses and shirts.
Lyocell is stronger than cotton or regular viscose
rayon and does not lose strength when wet as
viscose rayon does. Lyocell stretches more than
cotton, but less than viscose. It is often blended
with cotton and/or polyester, mainly in woven
fabrics, rather than knits. It is absorbent and
comfortable for wear in conditions of high
humidity because it is cellulosic which causes
moisture to be wicked away from your skin. It is
manufactured by a solvent spinning process, but
the solvent is recycled so its manufacture is an
environmentally friendly process compared to other
rayons.
Regarding the production of manufactured
fibers, a distinction should be made between
cellulosic and non-cellulosic fibers. Four
manufactured fibers - rayon, acetate, triacetate
and lyocell - are cellulosic fibers. This means
that one of the components used in their
production is natural cellulose. Cellulose is wood
pulp, generally obtained from trees. All of the
remaining manufactured fibers are non-cellulosic,
which means they are entirely chemically-based.
Cellulose is the natural polymer that makes up the
living cells of all vegetation. It is the most
abundant and replenishing biopolymer on earth.
What are the
properties of lyocell?
Lyocell breathes and
washes like cotton, yet has the soft, fluid,
natural draping qualities of rayon with a
luxurious and refined look. Lyocell has many
qualities and properties that make it an excellent
fabric:
·
Comfortable. It is soft,
breathable, lightweight and comfortable with a
feel similar to rayon.
·
Lasting. It is
shrink-resistant, durable and easy to care for.
It is an exceptionally strong fiber when wet or
dry.
·
Color rich. Lyocell fibers
are highly absorbent and bind well with dyes.
·
Easy to maintain. Lyocell
garments are easy to pack, resist wrinkling and
dry quickly. Most are machine washable.
·
Eco-friendly. Lyocell is made
from the natural cellulose found in wood pulp and
is biodegradable.
One of the interesting
properties of lyocell is its potential to
fibrillate. Fibrillation is where the wet fiber,
through abrasive action, develops micro-fibrils
(or tiny fibers) on its surface. By manipulating
or controlling fibrillation, a variety of
different fabric finishes may be achieved. For
example, the surface fibers of lyocell are often
fibrillated to produce a luxurious, soft-touch
fabric with a peach skin surface. Or, they can be
not fibrillated to create a surface finish that
has a subtle surface luster with excellent print
definition and high tear and burst strength for
woven and knitted fabrics.
Lyocell is often blended with other natural
fibers such as wool, cotton, silk, flax and
various manufactured fibers. When blended with
other fibers it gives a wonderful sheen to the
yarn and adds softness to many other fibers.
Cotton blended with lyocell becomes stronger and
wool/lyocell blends are more absorbent.
Lyocell was created to accept
color more readily. It can be dyed from the palest
tints through medium tones to vibrant, deep darks.
Garments made from lyocell are inherently soft and
smooth to the touch. The fabric drapes well in
soft, gentle folds. Depending on the finishes
applied during manufacturing, lyocell fibers can
feel like silk, cotton or wool, and still maintain
a washable quality.
How is lyocell
made?
Most people assume that there
are two general categories of fibers: natural ones, like
cotton, wool and silk; and artificial ones
synthesized out of petrochemicals like nylon and
polyester. Lyocell falls somewhere in-between. The
raw material for lyocell is cellulose, which is
broken down chemically and reformed as fibers.
Lyocell is more accurately described as a
recovered or regenerated fiber.
Some have heralded lyocell as
a new fiber that represents a milestone in the
development of environmentally sustainable
textiles. Lyocell is made from cellulose in wood
pulp, which is harvested from tree-farmed trees.
Cellulose is the natural polymer that makes up the
living cells of all vegetation. The fiber is
produced via an advanced 'closed loop' solvent
spinning process, with minimal impact on the
environment and economical use of energy and
water. It uses a non-toxic solvent which is
continually recycled during the production
process. Production plant emissions into the air,
from smokestacks, and water, from wastewater, are
significantly lower in comparison to many other
man-made fiber operations.
As with conventionally
manufactured cotton fabric, there are many steps
and processes involved in taking lyocell from
fiber to fabric. The major steps are:
-
Creating a solvent
solution from wood pulp
-
Spinning lyocell fiber
from the solvent solution
-
Washing lyocell fiber to
remove solvents
-
Drying fiber and producing
yarns
-
Finishing to produce
lyocell fabric
Let’s examine each step more
closely for the chemicals and processes used to
determine how ecological lyocell is.
Step 1. Creating a
solvent solution from wood pulp.
The cellulosic fibers (rayon, acetate,
triacetate and lyocell) come from purified wood
pulp, which first must be shredded and then
dissolved. The
manufacturing process for lyocell is based on the
principle of direct solvent spinning. In contrast
to common production processes, the cellulose in
wood pulp does not need any prior chemical
modification ("derivatization"), but it dissolves
in a purely physical manner, just like sugar in
water. The manufacturing process is characterized
by almost completely closed solvent and water
cycles. This reduces emissions significantly.
The wood pulp solution is
produced in a straight solvation process by
dissolving wood pulp at high temperatures and
pressure in a non-toxic organic solvent solution
of amine oxide, particularly N-methylmorpholine
N-oxide, which is reclaimed and recycled in
a “closed loop” spinning process conserving energy
and water. Up to 99% of the solvent is recovered
and reused. The wood pulp can come from a variety
of sources, such as wood chips or even large rolls
of paper that have been finely shredded, depending
upon the manufacturer’s technologies.
Amine oxide is an amphoteric
surfactant widely used in cleaning and personal
care products, usually in conjunction with other
surfactants. “Surfactants” is a scientific name
for surface-active soaps and cleaners. The major
uses are in laundry and cleaning products, where
it functions as a foam stabilizer, thickener and
emollient, emulsifying and conditioning agent.
Amine oxide biodegrades readily and completely
under aerobic and anaerobic conditions and can be
highly removed by conventional sewage treatment.
The acute toxicity varies between 1.7 and 5.3 ppm
and the chronic toxicity between 160 and 1100 ug/L.
Amine oxides have been used in shampoo, bubble
bath, and hand-soap formulations in conjunction
with alkyl sulfates and olefin sulfonates.
Step 2. Spinning
lyocell fiber from the solvent solution
Before being formed into
fibers, the fiber-producing substance for all
manufactured fibers is in a thick liquid state. In
the spinning process this liquid is forced through
a spinneret, which resembles a large shower head.
“Spinneretes” is the
same term used for the silk-producing organs on
spiders and caterpillars and their precise design
and manufacture is critical to the successful
formation of filaments.
A spinneret can have from one to literally
hundreds of tiny, finely machined holes in a steel
plate. The size of the holes varies according to
the size and type of the fiber being produced. These
holes are called Unlike natural fibers,
manufactured fibers can be extruded in different
thicknesses. This is called denier. Denier is a
term you may have heard, and essentially relates
to the fineness of the fiber filament. For
example, a twelve (12)-denier monofilament is
commonly used in sheer pantyhose, and a circular
double-knit is about 140-denier.
The clear, viscous resultant
solution is filtered and extruded into an aqueous
bath of dilute amine oxide, and coagulated into
fiber form. This process does not involve any
direct chemical reaction and the diluted amine
oxide is purified and reused. This makes for a
completely contained process fully compatible with
all environmental regulations.
Step 3. Washing
lyocell fiber to remove solvents.
The fiber is then washed
before it is dried and twisted or spun into yarns,
which are woven or knitted into fabrics and
garments.
No chemical intermediates are
formed during the solvent and spinning processes,
the minimal product byproduct waste and wastewater
are not hazardous, and energy consumption is low. This is the rational for calling lyocell a man-made
fiber that is natural in origin.
Step 4. Drying fiber and producing yarns.
When the filament dries or
solidifies, it forms what is called a continuous
filament fiber. Many continuous filaments of
specific thicknesses collected in a large bundle
called a "tow". A tow may contain over a million
continuous filaments. The tow bundle is then
crimped, in much the same way a curling iron is
used to crimp a woman's hair, and is then
mechanically cut into staple fibers, usually
ranging in length from 1 to 6-1/2 inches,
depending how they are to be used.
Strands of continuous
filament fibers are then twisted together to form
a continuous filament yarn, which is then woven or
knit into fabric.
Step 5. Finishing to produce lyocell fabric.
Due to the nature of lyocell
to fibrillate and take dyes poorly, the finishing
process is more complicated and takes longer than
for other cellulose fabrics. Lyocell fiber has a
relatively low surface energy, which makes it
difficult for dyes to bind to it. As we have
seen with other fibers, the dying processes can
have a large environmental impact and greatly
affect the wear-ability of the garment, especially
for those with chemical sensitivities.
Another characteristic of lyocell that is often
treated chemically during the fabric manufacturing
process is tendency of lyocell to fibrillate or
“pill”. One method to control fibrillation in
lyocell is to treat the fabric with an enzyme that
attacks cellulose fibers. Many home laundry
detergents contain a similar enzyme designed to
keep cotton looking newer longer and colors
brighter; the cotton symbol is used on these
detergent boxes. This enzyme dissolves the
split-end hairs from the fiber surface. The fiber
is then washed and agitated again. Some secondary
fibrillation will occur which produces a fabric
that looks sand-washed or like suede. The
resulting fabric is similar in texture and drape
to sueded silk or sueded rayon found in fashion
apparel. Fabrics processed this way can usually be
machine washed and line dried successfully.
Tossing these fabrics in the dryer with a damp
towel for a few minutes when dry or almost dry
will restore the softness and drape. This approach
to processing uses the tendency to fibrillate to
advantage to create a sand-washed textured fabric.
The enzyme is washed out and becomes part of the
waste water that must be treated.
Another alternative to preventing fibrillation is
chemical treatments in the last step of fiber and
fabric processing. Fabrics processed this way can
successfully be machine washed and tumble dried.
These fabrics will generally have a smooth
surface, such as chino for slacks and jackets, as
well as knits for both hosiery and sweaters.
Fabrics labeled as Lyocell® A-100 have been
treated with this process. The environmental
impact is that additional chemicals are added to
the manufacturing process and become part of the
waste treatment process … and problem.
Thickeners of CMC or
starch type thickeners are often added to lyocell
to prepare the fabric for weaving. If reactive
dyestuffs are used in the dyeing process, the
dyestuffs will react to the thickeners so that the
dyeing depth of the fiber surface becomes low or
uneven dyeing occurs.
The desizing and scouring processes typically
require a bath in enzymatic desizing agents and
the use of sodium carbonate. The crumpling
process is added with a dye bath lubricant.
Additional enzymatic treatments and strength loss
inhibitors are often required to remove
fibrillations caused by the crumpling process.
After enzymatic
treatment, the enzyme should be deactivated by
raising the temperatures to more than 70
and making the pH weakly alkaline by adding sodium
carbonate. If the enzyme remains within the
structure of lyocell fiber, the color yield of the
fiber will decrease, and furthermore uneven dyeing
may occur.
The processes for dyeing
lyocell are also complicated and involve a larger
number of steps and chemicals than for natural
fibers. The pH and temperature must be carefully
controlled depending upon the dyeing process to
create an even dyeing and to prevent
fibrillation. Multifunctional reactive dyestuffs
are commonly used.
Fibrillation in Lyocell Fibers.
A
better understanding of the lyocell fiber may help
explain the variation in care methods. A unique
property of lyocell is that the fibers
"fibrillate" when wet and are mechanically
agitated, like you would get in a washing machine.
When the fibers get wet, they swell and become
almost "boardy." Fibrillation is the peeling back
or splintering of the fiber ends to form tiny
"hairs" on the surface. Think of each fiber as a
banana. Small fibrils or sections of the fiber
splinter and pull away like a banana peel. These
surface fibers mat together and detract from the
appearance of the finished fabric. Fibrillation
can be handled by preventing it from happening or
by using it to advantage.
Fabrics made from lyocell that is not specially
treated to prevent fibrillation are usually
labeled as "dry clean only." Reduced moisture and
agitation during dry-cleaning prevent
fibrillation. Garments made this way should
perform satisfactorily if care recommendations are
followed.
Is lyocell ecologically important?
Lyocell is claimed to
be a natural, man-made fiber whose manufacturing
is environmentally friendly. The raw
material for lyocell comes from wood pulp from
trees grown on managed tree farms where replanting
rates exceed usage or from low-grade recycled
paper. The solvent to
digest the wood pulp is toxic but about 99% is
recovered and recycled. Waste products in
the air and water from the manufacturing process
are minimal and considered harmless. Lyocell fiber
is eco-friendly since products made from it can be
recycled and lyocell is biodegradable because it
is a cellulosic fiber; however it will not break
down completely if it is disposed of in a
landfill. Products made from lyocell can be
recycled, incinerated, or digested in sewage. The
fiber will degrade completely in just eight days.
Wood is the most significant
replenishable raw material. If forestry work is
conducted with care, wood offers the advantage of
a very low water consumption and space can be put
to optimum use compared to other natural
substances. This means that cellulose can be
extracted with a high content and the minimum use
of extraction agents.
The process to manufacture lyocell fiber
is in fact very nearly a closed loop process in
which bleach is not required. Bleach is commonly
required in fabric manufacturing, especially for
cotton. For this reason high quality lyocell
products contain no free chlorine and are sold as
so-called "TCF - products". The European Union
awarded this process the Environmental Award 2000
in the category "technology for sustainable
developments".
So we see that the manufacturing of lyocell
fiber does environmental and ecological benefits.
Most of concern about lyocell comes from the heavy
use of chemicals to turn lyocell fiber into
garments. Tencel is probably not appropriate for
those with Multiple Chemical Sensitivities.
What do we offer that is made from lyocell?
At LotusOrganics.com, we
offer a few select garments that are lyocell
/Tencel blends. We have tried to find
manufacturers that use lyocell that has been
lightly treated and undyed. Your thoughts and
comments about lyocell and lyocell garments would
be greatly appreciated. You can email us at
CustomerService@LotusOrganics.com. Also, your
feedback on the usefulness of this article would
be greatly appreciated.
You can check out the
following items:
Raglan Zip Cardigan
Hemp-Tencel Blouse

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